These two words mean exactly the same thing: liable to burst into flames.
Often the prefix in- indicates a negative, as in invulnerable, incapable, ineluctable, inorganic, inactive. But just as often, perhaps even more often, it does not: inculcate, inflatable, incubate, influence, insert.
For health and safety reasons, manufacturers have started using flammable rather than inflammable, lest some genius decide that a bottle of inflammable lighting fluid could not possibly explode and then sues them for his blistered face and incurable illiteracy.
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